Molecular Weight Of Nickel Dmg

Nickel(II) acetate

Names
Systematic IUPAC name
Identifiers
3D model (JSmol)	ionic form: Interactive image coordination form (anhydrate): Interactive image coordination form (tetrahydrate): Interactive image
ECHA InfoCard	100.006.147
EC Number
PubChemCID
CompTox Dashboard(EPA)
InChI=1S/2C2H4O2.Ni/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
ionic form: [Ni+2].[O-]C(=O)C.[O-]C(=O)C coordination form (tetrahydrate): O=C(C)O[Ni-4](OC(C)=O)([O+H2])([O+H2])([O+H2])[O+H2]
Properties
C4H6NiO4
Molar mass	176.781 g·mol−1
Appearance	Green Solid
Odor	slight acetic acid
Density	1.798 g/cm3 (anhydrous) 1.744 g/cm3 (tetrahydrate)
Melting point	decomposes when heated [1][2]
Easily soluble in cold water, hot water
Solubility	Soluble in methanol insoluble in diethyl ether, n-octanol
+4,690.0·10−6 cm3/mol
Structure
monoclinic
P21/c
α = 90°, β = 93.6°, γ = 90°[3]
Lattice volume (V)	471.5
2
distorted octahedral
Hazards
NFPA 704 (fire diamond)
Lethal dose or concentration (LD, LC):
350 mg/kg (rat, oral) 410 mg/kg (mouse, oral)[4]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

1. Molecular Weight Of Nickel Dmg In Mac
2. Molecular Weight Of Nickel Dmg 2
3. Structure Of Nickel Dmg Complex
4. Molecular Weight Of Nickel Dmg Complex

Nickel(II) acetate is the name for the coordination compounds with the formula Ni(CH₃CO₂)₂·x H₂O where x can be 0, 2, and 4. The green tetrahydrate Ni(CH₃CO₂)₂·4 H₂O is most common. It is used for electroplating.

Weight of sample 100 Theoretical weight percent of nickel Weight of DMG 2 G F. From the experiment, the weight percent of nickel (II) ions that present in the nickel ammonium sulphate was 18.17%. The theoretical percent is 14086%. A novel dimethylglyoxime (DMG)/poly(caprolactone) (PCL) blend was electrospun into fibers to serve as an optical sensor for the nickel detection based on the formation of a red Ni(DMG)(2) complex.

Molecular Weight Of Nickel Dmg In Mac

Synthesis and structure[edit]

The compound can be prepared by treating nickel or nickel(II) carbonate with acetic acid:

NiCO₃ + 2 CH₃CO₂H + 3 H₂O → Ni(CH₃CO₂)₂·4 H₂O + CO₂

The green tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central nickel centre being coordinated by four water molecules and two acetate ligands.^[5] It may be dehydrated in vacuo, by reaction with acetic anhydride,^[6] or by heat.^[7]

Molecular Weight Of Nickel Dmg 2

Safety[edit]

Nickel salts are carcinogenic and irritate the skin.

Structure Of Nickel Dmg Complex

References[edit]

1. ^M. A. Mohamed, S. A. Halawy, M. M. Ebrahim: 'Non-isothermal decomposition of nickel acetate tetrahydrate', in: Journal of Analytical and Applied Pyrolysis, 1993, 27 (2), S. 109–110. doi:10.1016/0165-2370(93)80002-H.
2. ^G. A. M. Hussein, A. K. H. Nohman, K. M. A. Attyia: 'Characterization of the decomposition course of nickel acetate tetrahydrate in air', in: Journal of Thermal Analysis and Calorimetry, 1994, 42, S. 1155–1165; doi:10.1007/BF02546925.
3. ^Downie, T. C.; Harrison, W.; Raper, E. S.; Hepworth, M. A. (15 March 1971). 'A three-dimensional study of the crystal structure of nickel acetate tetrahydrate'. Acta Crystallographica Section B. 27 (3): 706–712. doi:10.1107/S0567740871002802.
4. ^'Nickel metal and other compounds (as Ni)'. Immediately Dangerous to Life and Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
5. ^Van Niekerk, J. N.; Schoening, F. R. L. (1953). 'The crystal structures of nickel acetate, Ni(CH₃COO)₂·4H₂O, and cobalt acetate, Co(CH₃COO)₂·4H₂O'. Acta Crystallogr.6 (7): 609–612. doi:10.1107/S0365110X5300171X.
6. ^Lascelles, Keith; Morgan, Lindsay G.; Nicholls, David; Beyersmann, Detmar (2005). 'Nickel Compounds'. Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_235.pub2.
7. ^Tappmeyer, W. P.; Davidson, Arthur W. (1963). 'Cobalt and Nickel Acetates in Anhydrous Acetic Acid'. Inorg. Chem.2 (4): 823–825. doi:10.1021/ic50008a039.

Molecular Weight Of Nickel Dmg Complex

AcOH

He

LiOAc

Be(OAc)2 BeAcOH

B(OAc)3

AcOAc ROAc

NH4OAc

AcOOH

FAc

Ne

NaOAc

Mg(OAc)2

Al(OAc)3 ALSOL Al(OAc)2OH Al2SO4(OAc)4

Si

P

S

ClAc

Ar

KOAc

Ca(OAc)2

Sc(OAc)3

Ti(OAc)4

VO(OAc)3

Cr(OAc)2 Cr(OAc)3

Mn(OAc)2 Mn(OAc)3

Fe(OAc)2 Fe(OAc)3

Co(OAc)2, Co(OAc)3

Ni(OAc)2

Cu(OAc)2

Zn(OAc)2

Ga(OAc)3

Ge

As(OAc)3

Se

BrAc

Kr

RbOAc

Sr(OAc)2

Y(OAc)3

Zr(OAc)4

Nb

Mo(OAc)2

Tc

Ru(OAc)2 Ru(OAc)3 Ru(OAc)4

Rh2(OAc)4

Pd(OAc)2

AgOAc

Cd(OAc)2

In

Sn(OAc)2 Sn(OAc)4

Sb(OAc)3

Te

IAc

Xe

CsOAc

Ba(OAc)2

Hf

Ta

W

Re

Os

Ir

Pt(OAc)2

Au

Hg2(OAc)2, Hg(OAc)2

TlOAc Tl(OAc)3

Pb(OAc)2 Pb(OAc)4

Bi(OAc)3

Po

At

Rn

Fr

Ra

Rf

Db

Sg

Bh

Hs

Mt

Ds

Rg

Cn

Nh

Fl

Mc

Lv

Ts

Og

↓

La(OAc)3

Ce(OAc)x

Pr

Nd

Pm

Sm(OAc)3

Eu(OAc)3

Gd(OAc)3

Tb

Dy(OAc)3

Ho(OAc)3

Er

Tm

Yb(OAc)3

Lu(OAc)3

Ac

Th

Pa

UO2(OAc)2

Np

Pu

Am

Cm

Bk

Cf

Es

Fm

Md

No

Lr

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